Nylon 3

Nylon 3

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Affiliation

1 Department of Chemistry, University of Wisconsin, Madison, Wisconsin 53706, USA.

Runhui Liu et al.

J Am Chem Soc .

2013 .

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Abstract

PubMed

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Affiliation

1 Department of Chemistry, University of Wisconsin, Madison, Wisconsin 53706, USA.

Representative sequence- and stereo-random nylon- 3 co-polymer containing subunits derived from racemic cis- cyclohexyl β-lactam ( CH ) and racemic monomethyl aminomethyl β-lactam ( MM ). R represents the side chain group for either CH or MM . This co-polymer inhibits the growth of several bacterial species at relatively low concentrations but is only weakly hemolytic.
β-Lactams and corresponding hydrophilic (cationic) subunits within the nylon-3 polymer chain. All β-Lactams are racemic, and the resulting polymers are heterochiral.
The synthesis of racemic β-lactam NM .
The structure of CH:NM co-polymers. All copolymers are heterochiral and sequence-random. x + y = 100, y = 40, 50, 60, 70, 80, or 90. R represents the side chain group of either CH or NM .

Liu R, Chen X, Falk SP, Mowery BP, Karlsson AJ, Weisblum B, Palecek SP, Masters KS, Gellman SH.
Liu R, et al.
J Am Chem Soc. 2014 Mar 19;136(11):4333-42. doi: 10.1021/ja500036r. Epub 2014 Mar 7.
J Am Chem Soc. 2014.

PMID: 24606327
Free PMC article.

Rank LA, Walsh NM, Lim FY, Gellman SH, Keller NP, Hull CM.
Rank LA, et al.
mSphere. 2018 May 23;3(3):e00223-18. doi: 10.1128/mSphere.00223-18. eCollection 2018 May-Jun.
mSphere. 2018.

PMID: 29794056
Free PMC article.

Liu R, Chen X, Chakraborty S, Lemke JJ, Hayouka Z, Chow C, Welch RA, Weisblum B, Masters KS, Gellman SH.
Liu R, et al.
J Am Chem Soc. 2014 Mar 19;136(11):4410-8. doi: 10.1021/ja500367u. Epub 2014 Mar 7.
J Am Chem Soc. 2014.

PMID: 24601599
Free PMC article.

Mowery BP, Lindner AH, Weisblum B, Stahl SS, Gellman SH.
Mowery BP, et al.
J Am Chem Soc. 2009 Jul 22;131(28):9735-45. doi: 10.1021/ja901613g.
J Am Chem Soc. 2009.

PMID: 19601684

Sharma M, Joshi P, Kumar N, Joshi S, Rohilla RK, Roy N, Rawat DS.
Sharma M, et al.
Eur J Med Chem. 2011 Feb;46(2):480-7. doi: 10.1016/j.ejmech.2010.11.027. Epub 2010 Nov 24.
Eur J Med Chem. 2011.

PMID: 21163555

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Host-defense peptides inhibit bacterial growth but show little toxicity toward mammalian cells. A variety of synthetic polymers have been reported to mimic this antibacterial selectivity; however, achieving comparable selectivity for fungi is more difficult because these pathogens are eukaryotes. Here we report nylon-3 polymers based on a novel subunit that display potent antifungal activity (MIC = 3.1 μg/mL for Candida albicans ) and favorable selectivity (IC10 > 400 μg/mL for 3T3 fibroblast toxicity; HC10 > 400 μg/mL for hemolysis).

Representative sequence- and stereo-random nylon-…
Representative sequence- and stereo-random nylon- 3 co-polymer containing subunits derived from racemic cis-…
β-Lactams and corresponding hydrophilic (cationic)…
β-Lactams and corresponding hydrophilic (cationic) subunits within the nylon-3 polymer chain. All β-Lactams…
The synthesis of racemic β-lactam NM .
The structure of CH:NM co-polymers.…
The structure of CH:NM co-polymers. All copolymers are heterochiral and sequence-random. x +…

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Nylon rope has high elongation (under load) when compared to other synthetic ropes. Nylon has high energy absorption under shock and good abrasion resistance. When combined, these characteristics makes nylon rope the best in handing compared to other synthetics. It's utilized extensively in marine use such as mooring lines, towing slings, commercial fishing, utility rope, leasure boat, sailing etc.
[Nylon fiber 3, 8 ST]
*Fiber Content: Nylon fiber
*Specific gravity: 1.14
*Melting point: 220 °c
*Elongation at break: 45%
*Water absorption: 2-5%
[Nylon fiber 12S/T
*Fiber Content: Nylon fiber
*Specific gravity: 1.14
*Melting point: 220 °c
*Elongation at break: 30%
*Water absorption: 2-5%
Applications
*Mooring lines
*Towing Lines
*Anchor Lines

From Wikipedia, the free encyclopedia
Family of synthetic polymers originally developed as textile fibres
For other uses, see Nylon (disambiguation) .

^ The polyamides may be aliphatic or semi-aromatic .

^ Actually the most common nylon polymers are made from hexamethylenediamine, with one more CH 2 group than cadaverine.

^ Typically 80 to 100% is sent to landfill or garbage dumps, while less than 18% are incinerated while recovering the energy. See Francesco La Mantia (August 2002). Handbook of plastics recycling . iSmithers Rapra Publishing. pp. 19–. ISBN 978-1-85957-325-9 .

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^ "Global Nylon Market Analysis and Outlook 2020-2027 - Nylon 6" .

^ "Market Report: Global Polyamide Market" . Acmite Market Intelligence. December 2014.

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^ Rudin, Alfred (1
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