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Conservation of ultrafast photoprotective mechanisms with increasing molecular complexity in sinapoyl malate derivatives - Baker - 2020 - ChemPhysChem - Wiley Online LibrarySome Known Factual Statements About Final Fantasy Brave Exvius - Ultimate Pop Culture Wiki - Fandom
Open Access, Article 1 Institute of Physical and Theoretical Chemistry, Goethe University Frankfurt am Main, Max-von-Laue Strae 7, 60438 Frankfurt, Germany 2 Institute of Biophysics, Goethe University Frankfurt am Main, Max-von-Laue Strae 1, 60438 Frankfurt, Germany 3 Department of Chemistry, Philipps-Universitt Marburg, Hans-Meerwein-Strae 4, 35032 Marburg, Germany 4 Center for Synthetic Microbiology, Philipps-Universitt Marburg, Hans-Meerwein-Strae 6, 35032 Marburg, Germany * Authors to whom correspondence must be resolved.
Knotless phytochromes are among the 3 main subgroups classified by their distinct lack of the PAS domain in their photosensory core module, which remains in contrast to the canonical PAS-GAF-PHY range. In Solution Can Be Seen Here of intensive research on the ultrafast photodynamics of phytochromes, little is learnt about the primary kinetics in knotless phytochromes.
Our results reveal that the excited state life time of Pr * (200 ps) resembles bacteriophytochromes, however a lot longer than in many canonical phytochromes. We designate the slow Pr * kinetics to relaxation processes of the chromophore-binding pocket that manages the bilin chromophore's isomerization step. The Pfr photoconversion dynamics starts with a faster thrilled state relaxation than in canonical phytochromes, but, regardless of the differences in the particular domain architectures, proceeds by means of similar ground state intermediate steps up to Meta-F.
e., readily available area and flexibility) within the binding pocket, while the general response steps following the photoexcitation are probably conserved amongst the red/far-red phytochromes.
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