Стаф в Шихане
Стаф в ШиханеСтаф в Шихане
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Skip to main content. Log In Sign Up. Yale University , Chemistry , Graduate Student. A molecular catalyst for water oxidation that binds to metal oxide surfaces. Molecular catalysts are known for their high activity and tunability, but their solubility and li Here we describe how a molecular iridium catalyst for water oxidation directly and robustly binds to oxide surfaces without the need for any external stimulus or additional linking groups. On conductive electrode surfaces, this heterogenized molecular catalyst oxidizes water with low overpotential, high turnover frequency and minimal degradation. Spectroscopic and electrochemical studies show that it does not decompose into iridium oxide, thus preserving its molecular identity, and that it is capable of sustaining high activity towards water oxidation with stability comparable to state-of-the-art bulk metal oxide catalysts. Hematite-based solar water splitting: Semiconductor nanostructure-based photoelectrochemical water splitting: Recent efforts on solar water splitting by nanoscale semiconductor materials is reviewed. Nanostructures of varying complexities, from one-dimensional nanotubes, nanowires, and nanorods, to two-dimensional films and nanonets, and three-dimensional porous structures have been reported to exhibit superior performance. We also summarize recent successes in advancing the field by heterogeneous nanostructures, which make it possible to achieve combined functionalities not observed with single-component materials. Synthesis and Energetic Applications. Nanonet-based hematite heteronanostructures for efficient solar water splitting. Journal of the American Chemical Society , Water splitting by tungsten oxide prepared by atomic layer deposition and decorated with an oxygen-evolving catalyst. Angewandte Chemie International ed. Photoactive TiO 2 served to convert incident photons into separated charges, and the supporting TiSi 2 nanonet acted as an efficient conductor to transport separated charges. The structural complexity of TiSi 2 also provided a framework of high surface area to enhance photoabsorption. The TiO 2 growth was further explored to extend the absorption to the visible range by incorporating W into TiO 2 , and 0. Remember me on this computer. Click here to sign up. Help Center Find new research papers in:
Работа: в Шиханах, 0 вакансий
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