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Solution pH is an important factor during drug formulation and processing. Changes in pH present challenges. Regulation of pH is typically managed by using a buffer system, which must have a suitable pK a. The pK a of buffers depends on temperature, pressure and ionic strength. In addition, the pK a can also be affected by the polarity of the solvent, e. Theoretical considerations and accessible experimental data were used to understand how the pK a values of pharmaceutically relevant buffers depend on these factors. Changes in temperature also affect the buffer pK a. Carboxylic acid moieties were least affected by changes in temperature. Buffers containing amino groups were most affected by changes in temperature, and the pK a decreased as temperature was increased. It was possible to predict accurately how buffer pK a varies with temperature, based on changes in enthalpy and heat capacity for the ionization reactions. At higher pressures, buffer pK a varied by up to 0. Altering the ionic strength or polarity of the solvent influenced buffer pK a slightly. However, it is possible to keep both the ionic strength and the polarity of the solvent constant during drug formulation and processing. Keywords: Autoclaving; Chemical thermodynamics; Liquid formulations; Pharmaceutical processing; Temperature-dependency; pH. Abstract Solution pH is an important factor during drug formulation and processing.

La Thuile 2021 - Les Rencontres de Physique de la Vallée d'Aoste

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The format of our Workshop will be adapted to the media in order to facilitate the participation from remote. The sessions of Young Since Forum are reserved to PhD students, in both experimental and theoretical physics. Choose timezone Your profile timezone:. The format of our Workshop will be adapted to the media in order to facilitate the participation from remote The sessions of Young Since Forum are reserved to PhD students, in both experimental and theoretical physics. Tuesday, March 9. ALPS and Axions 20m. Speaker : Andrea Thamm Melbourne University. Young Scientist Forum: I. Neutrino quantum decoherence at reactor experiments 12m. Speaker : Prof. Most recent results from T2K 20m. Primordial Nanoblackholes 20m. Speaker : Antonio Riotto University of Geneva. Dark Energy and GW Observations 20m. Young Scientist Forum: II. PeV Neutrinos 20m. Wednesday, March LaThuile Flavor fits 20m. Exotic hadrons: recent LHCb discoveries 20m. Speaker : Zehua Xu Peking University. Beauty baryons spectroscopy at LHCb 12m. Speaker : Viacheslav Matiunin. Measurements of charmless B decays at Belle II 12m. Flavour II and g Recent Results from Belle II 20m. Speaker : Ezio Torassa PD. Rare decays from NA62 20m. Speaker : Viacheslav Duk PG. New physics flavor model 20m. Young Scientist Forum: IV. La Thuile Manzari. Theoretical improvements on g-2 20m. Speaker : Gilberto Colangelo Berna University. Hunting for new physics with leptonic g-2 20m. Speaker : Paride Paradisi Padova U. Thursday, March Five years of gravitational waves observations: where we stand 20m. Towards the Muon Collider 20m. Speaker : Donatella Lucchesi PD. Electroweak precision tests of the SM: status and prospects 20m. La Thuile Speaker : Jeff Dandoy University of Pennslyvania. Young Scientist Forum: V. Electroweak corrections to the angular coefficients of finite-pT Z-boson production at pp colliders 12m. Speaker : Timea Vitos Lund University. Speaker : Manuel Guth University of Freiburg. Recent theory progress in QCD 20m. Speaker : Francesco Hautmann University of Oxford. Young Scientist Forum: VI. Evidence for Higgs decay to a pair of muons 12m. Speaker : Irene Dutta. The Faser experiment 20m. Speaker : Anna Sfyrla Geneva. Crunching away the hierarchy problem 20m. Speaker : Csaba Csaki Cornell University. La Thuile Crunching. Powered by Indico v3.

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