High Hole

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: stopping or resting on a line that is roughly even with the hole one is playing toward

— used of an approach shot in golf

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“Hole-high.” Merriam-Webster.com Dictionary , Merriam-Webster, https://www.merriam-webster.com/dictionary/hole-high. Accessed 14 Oct. 2022.
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Affiliations

1 Department of Chemical Sciences , Indian Institute of Science Education and Research (IISER) Mohali , Sector-81 , Sahibzada Ajit Singh Nagar, Knowledge City , Manauli 140306 , India.

2 Department of Physics , Patna University , Patna , Bihar 800005 , India.

3 Interdisciplinary Centre for Energy Research (ICER) , Indian Institute of Science (IISc) Bangalore , C. V. Raman Road , Bangalore , Karnataka 560012 , India.

Joydip De et al.

J Am Chem Soc .

2019 .

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1 Department of Chemical Sciences , Indian Institute of Science Education and Research (IISER) Mohali , Sector-81 , Sahibzada Ajit Singh Nagar, Knowledge City , Manauli 140306 , India.

2 Department of Physics , Patna University , Patna , Bihar 800005 , India.

3 Interdisciplinary Centre for Energy Research (ICER) , Indian Institute of Science (IISc) Bangalore , C. V. Raman Road , Bangalore , Karnataka 560012 , India.

Karak S, Liu F, Russell TP, Duzhko VV.
Karak S, et al.
ACS Appl Mater Interfaces. 2014 Dec 10;6(23):20904-12. doi: 10.1021/am505572v. Epub 2014 Nov 21.
ACS Appl Mater Interfaces. 2014.

PMID: 25393015

Kushida T, Shuto A, Yoshio M, Kato T, Yamaguchi S.
Kushida T, et al.
Angew Chem Int Ed Engl. 2015 Jun 1;54(23):6922-5. doi: 10.1002/anie.201502678. Epub 2015 Apr 23.
Angew Chem Int Ed Engl. 2015.

PMID: 25907576

Ma T, Zhong YJ, Wang HF, Zhao KQ, Wang BQ, Hu P, Monobe H, Donnio B.
Ma T, et al.
Chem Asian J. 2021 May 3;16(9):1106-1117. doi: 10.1002/asia.202100173. Epub 2021 Mar 23.
Chem Asian J. 2021.

PMID: 33704900

Termine R, Golemme A.
Termine R, et al.
Int J Mol Sci. 2021 Jan 16;22(2):877. doi: 10.3390/ijms22020877.
Int J Mol Sci. 2021.

PMID: 33467214
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Review.

Sergeyev S, Pisula W, Geerts YH.
Sergeyev S, et al.
Chem Soc Rev. 2007 Dec;36(12):1902-29. doi: 10.1039/b417320c. Epub 2007 Jul 3.
Chem Soc Rev. 2007.

PMID: 17982517

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Heterocoronene, a new redox-active core fragment, is utilized for the synthesis of room-temperature columnar discotic liquid crystals (DLCs). Three wedge-shaped side chains having different lengths of alkyl tails are introduced at the periphery of the heterocoronene core to prepare three kinds of discotic molecules, 1 (R = C 10 H 21 ), 2 (R = C 12 H 25 ), and 3 (R = C 14 H 29 ). X-ray diffraction (XRD) analysis confirmed the packing variation in the columnar lattices regulated by alkyl chains of discrete length and steric bulk. When used in space charge limited current devices, compound 1 exhibits a high hole mobility value of 8.84 cm 2 /V s at ambient temperature, whereas compounds 2 and 3 show efficient ambipolar charge transport behavior with maximum hole ( μ h ) and electron ( μ e ) mobilities of 0.70 and 3.59 cm 2 /V s, respectively, for compound 3 . The mobility values ( μ h = 8.84 cm 2 /V s for 1 and μ e = 3.59 cm 2 /V s for 3 ) are remarkable and the highest ever disclosed for any DLC-based organic semiconductor, promising to deliver a good balance between mobility and processability in devices. The grazing incidence small- and wide-angle X-ray scattering experiments are employed to quantify the extent of alignment in the film state, which correlates with the observed trend of mobility values.

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