Голубоглазая Lachia A ненавидит бриться

Голубоглазая Lachia A ненавидит бриться




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Голубоглазая Lachia A ненавидит бриться





LaChia L. Bradshaw takes office as Burlington County Acting Prosecutor




PUBLISHED: June 2, 2022 at 10:58 a.m. | UPDATED: June 2, 2022 at 10:59 a.m.

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A 20-year veteran of the Burlington County Prosecutor’s Office (BCPO) was sworn May 31 to oversee the agency, marking the first time in its history that the BCPO will be led by a person of color or a woman.
LaChia L. Bradshaw was administered the oath of office at the Olde Historic Courthouse in Mount Holly by the Hon. Terrence R. Cook, P.J.Cr. She met with members of the office immediately afterwa . . .
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LaChia L. Bradshaw sworn in as Burlington County Prosecutor



Names Brenda Román Maneri her second in command
PUBLISHED: July 14, 2022 at 1:04 p.m. | UPDATED: July 14, 2022 at 1:05 p.m.

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LaChia L. Bradshaw was sworn in July 11 as Burlington County Prosecutor during a groundbreaking ceremony marking the first time in the BCPO’s history that a person of color or a woman has taken the oath to oversee the agency for a full-length term.
After being nominated by Governor Murphy last month, Prosecutor Bradshaw emphasized that representation matters when it comes to prominent public positi . . .
We invite you to use our commenting platform to engage in insightful conversations about issues in our community. We reserve the right at all times to remove any information or materials that are unlawful, threatening, abusive, libelous, defamatory, obscene, vulgar, pornographic, profane, indecent or otherwise objectionable to us, and to disclose any information necessary to satisfy the law, regulation, or government request. We might permanently block any user who abuses these conditions.

This page lists the scientific contributions of an author, who either does not have a ResearchGate profile, or has not yet added these contributions to their profile. It was automatically created by ResearchGate to create a record of this author's body of work. We create such pages to advance our goal of creating and maintaining the most comprehensive scientific repository possible. In doing so, we process publicly available (personal) data relating to the author as a member of the scientific community. If you're a ResearchGate member, you can follow this page to keep up with this author's work. If you are this author, and you don't want us to display this page anymore, please let us know .
Purpose
Arbuscular mycorrhizal fungi (AMF) play important roles in agriculture because of their ability to improve plant resilience against abiotic and biotic stresses. AMF as a technology to promote a more sustainable agriculture holds great potential, yet many factors affect the efficiency of this plant-microbe symbiosis leading to inconsistency...
Strigolactones are a family of plant secondary metabolites whose first member strigol was isolated in 1966 from the root exudates of cotton and identified as the germination inducer for the parasitic weeds of Striga and Orobanche species. Since 2008 the role of strigolactones as a new class of phytohormones has emerged and their role in controlling...
Strigolactones have been known as signaling molecules in the rhizosphere of plants since more than 50 years. However, their roles as phytohormone have been only recognized since 2008. We describe here a very efficient synthetic access to representative canonical strigolactones displaying
the A-B-C-D tetracyclic structure and to non-canonical strigo...
Karrikin (KAR1) also named “karrikinolide” was isolated in 2004 from smoke water and identified as a very potent germination stimulant as well as controlling early seedling development for a large variety of plant species. We reported herein an unprecedented and scalable synthesis of Karrikin KAR1 based on an elegant and efficient 6‐endo‐dig cyclis...
γ-Lactams are important building blocks for the synthesis of biologically active molecules and can easily be accessed via Beckmann rearrangement of cyclobutanones. However, Beckmann fragmentation is often a competing reaction for these strained ketones. We found that performing the Beckmann rearrangement with Tamura’s reagent in the presence of aqu...
A systematic investigation of structural modifications of brassinosteroids is presented. We describe in detail their synthetic preparation, which includes significant improvements of previously reported protocols as well as access to new analogs with functional modifications of the steroid skeleton and of the C(17)-attached side chain. We report th...
Background:
Strigolactones play an important role in the rhizosphere as signaling molecules stimulating the seed germination of parasitic weed seeds and hyphal branching of arbuscular micorrhiza and also act as hormones in plant roots and shoots. Strigolactone derivatives e.g. strigolactams could be used as suicidal germination inducers in the abs...
New technologies able to mitigate the main abiotic stresses (i.e., drought, salinity, cold and heat) represent a substantial opportunity to contribute to a sustainable increase of agricultural production. In this context, the recently discovered phytohormone strigolactone is an important area of study which can underpin the quest for new anti-stres...
Very recently, strigolactones have been conclusively identified as phytohormones. The progresses achieved in this field are culminating in the identification of the molecular receptors involved in the signal transduction mechanism. The exact mechanism of the mode of action of strigolactones still remains to be fully elucidated and we were intereste...
The present invention relates to novel strigolactam derivatives of formula (I) to processes and intermediates for preparing them, to plant growth regulator compositions comprising them and to methods of using them for controlling the growth of plants and/or promoting the germination of seeds.
Two approaches to the strigolactone tricyclic lactone skeleton 2 were investigated using ketene/ketene-iminium cycloaddition to olefins. Finally, the first enantioselective access to the four stereoisomers of 5-deoxystrigol 1 is reported using an intramolecular [2+2] cycloaddition of homochiral ketene-iminium salts 5. Very high asymmetric control w...
NOVELTY - Non-steroidal brassinosteroid mimetic derivatives (I) are new.

USE - (I) are useful: in a plant growth regulator or seed germination promoting composition; for regulating the growth of plants at a locus; for promoting the germination of seeds; and for controlling weeds (all claimed). The ability of (I) to improve the growth of the plants...
Seed germination and early seedling development are essential events in the plant life cycle that are controlled largely by the interplay and cross-talk between several plant hormones. Recently, major progress has been achieved in the elucidation at the molecular level of the signalling
of these phytohormones. In this review, we summarise the data...
NOVELTY - Substituted 2-aminopyridine derivative (I), its salt and/or N-oxide is new.

USE - As a plant growth regulator or a seed germination promoter; for regulating the growth of plants at a locus; for promoting the germination of seeds; and for controlling weeds (claimed).

ADVANTAGE - The compound result in improved plant growth properties, su...
NOVELTY - Substituted amino azole derivatives (I) are new.

USE - (I) including the excluded compounds are useful for regulating the growth of plants at a locus, germination of seeds and controlling weeds (all claimed), where the plants are e.g. wheat, barley, rye, oats, sugar beet, apples, pears, plums, peaches, cherries, strawberries, raspberries...
An intramolecular 6 phi/10 pi-electrocyclization from ketene-iminium salts was developed for the preparation of naphthylamines. Various substituents on the nitrogen, on the aromatic ring, and on the olefin were studied. Tricyclic skeletons were obtained in few steps and good overall yields. The electrocyclization of ketene-iminium salts has been co...
Strigolactones have been the latest identified phytohormones. Among the strigolactones analogues described recently, GR-24 remains the most studied derivative which is used as standard in this field. In order to improve several properties of GR-24 for potential agronomical applications, we investigated the effect of substituents on the B and C-ring...
NOVELTY - Substituted pyrrolidine containing heterocyclic compounds (I) are new.

USE - (I) are useful as plant growth regulators or seed germination promoters and for controlling weeds (claimed) in e.g. cereals (wheat, barley, rye and oats), beet (sugar beet or fodder beet), fruits (pomes, apples, pears, plums, peaches, almonds, cherries, strawber...
NOVELTY - A non-steroidal brassinosteroid mimetic pyridine derivative (I), or its salt or N-oxide, is new.

USE - As a plant growth regulator or seed germination promoting composition; for regulating the growth of plants at a locus; for controlling weeds; and for promoting the germination of seeds (claimed). The plant includes crops such as cereals...
NOVELTY - Substituted 2-amino-pyridine compounds (I) are new.

USE - (I) are useful for regulating the growth of plants at a locus, promoting the germination of seeds, and controlling weeds (all claimed). The ability of (I) to regulate plant growth was tested on French beans (Phaseolus vulgaris) by measuring the length of the petiole of the second...
An intramolecular [2+2] cycloaddition of ketenes and ketene-iminium was developed for the preparation of GR-24, a synthetic analogue of the family of strigolactone plant hormones. Excellent levels of regioselectivity and of chiral induction were obtained using a bulky chiral amine for the formation of the cyclobutanone and a subsequent regioselecti...
We report here the use of the readily accessible ethyl-2-(2-chloroethyl)acrylate as a new very versatile α-cyclopropylester cation synthon, which reacts efficiently and selectively with carbon-, nitrogen-, sulfur- or phosphorus-centered nucleophiles through Michael addition followed by intramolecular capture of the incipient ester enolate to afford...
... Recent research examining the chemical basis of nematode herbivory in Capsicum spp (Kihika et al., 2017) illustrates the potential of using this strategy for belowground pests, though there are many more examples of modulating behavior of pests aboveground through push-pull systems (Cook et al., 2007;Xu et al., 2018;Rivera et al., 2020). Beyond "push-pull" systems there are numerous opportunities to innovate novel methods of pest control-that regulate soil communities using root exudate chemistries (Chaparro et al., 2012), plant-microbe or other symbioses, (Mercado-Blanco and Bakker, 2007; Borghi et al., 2021) , mediation of tri-trophic interactions, (Helmberger et al., 2017), and improved cycling of crop limiting nutrients (Moreau et al., 2019)-and reach soil health goals. ...
... The desire to avoid impacts that are not well understood has driven increasing attention within both the policy and R&D communities on technologies that decrease reliance on chemical pest control methods and reduce inputs. This includes strategies to elicit natural plant defenses and immune responses through priming (Worrall et al., 2011), advanced breeding techniques/genetic modification (Bruce, 2012), or plant-or microbe-derived molecules (Wiesel et al., 2014), including plant hormones (De Mesmaeker et al., 2019) . One novel approach for eliciting or enhancing plant defenses is through the use of RNA (hostinduced sRNA, dsRNA, or RNAi) for targeted gene silencing in fungal pathogens (Niu et al., 2021). ...
... Chemical modulators of ABA perception have been sought as both research tools for dissecting ABA's role in plant physiology and for their potential agricultural utility (6,7). Dozens of ABA receptor agonists, which reduce transpiration and water use by inducing guard cell closure, have been developed and are being explored as chemical tools for mitigating the effects of drought on crop yields (7)(8)(9)(10)(11)(12)(13)(14)(15)(16)(17)(18)(19)(20)(21)(22) (23) , most of them either being analogs of ABA or sulfonamides similar to quinabactin (24). ABA receptor antagonists could conceivably be useful in cases where water is not limiting, for example, to increase transpiration and gas exchange under elevated CO 2 in glasshouse agriculture, as germination stimulators, and for studying the ABA dependence of physiological processes, among other applications (25)(26)(27)(28)(29)(30)(31). ...
... More data about SL bioavailability and stability in plants and soil are certainly required, and the levels of uptake following application under field conditions should be determined. The fast degradation of natural and synthetic SLs in soil [107], and the limited information on early chemical uptake into seeds are major limits [108] . Finally, more clarity is required in the legislation on the production, commercialization and use of potential future SL-based technologies [7]. ...
... The declining order of activity 2α, 3α > 2α, 3β > 2β, 3α > 2β, 3β suggests that the αoriented hydroxyl group at C-2 is essential for biological activity of BRs in plants [24,25]. On the basis of cholestane side chain, BRs have been divided by different substituents into C-23, C-24, and C-25: 23-oxo (4 compounds), 24-methylene (3 compounds), 24S-ethyl (4 compounds), 24R-methyl (5 compounds), 24S-methyl (23 compounds), C-25, 24-ethylidene (3 compounds), 24-methyl-25-methyl (3 compounds), 24-methylene-25-methyl (6 compounds) without substituent at C-23 (3 compounds), without substituent at C-24 (8 compounds), and without substituents at C-23, C-24 (2 compounds) [26] [27][28]. ...
... SLs act as plant growth and developmental regulators endogenously in the plant's organism and exogenously in the rhizosphere at very low concentrations [47]. The pleiotropic roles played by SLs in plants under the absence of the stress-factor and during plant adaptation to environmental changes can pave the way for new innovative productivity enhancement applications [284] . ...
... This moiety corresponds with the bioactiphore, the part that is primarily responsible for the bioactivity of the molecule . Some examples of bioactive compounds belonging to this type of derivatives (proven to be active as parasitic germination or branching arbuscular mycorrhizal fungi stimulators) are shown in Fig. 2 (Hýlová et al. 2019;Kondo et al. 2007; Lumbroso et al. 2016; Zwanenburg et al. 2016Zwanenburg et al. , 2009). With special emphasis, compounds MP1, MP3, MP13 and MP26 have shown promising results in the germination of the problematic parasitic weed Striga hermonthica, including in greenhouse and field trials through suicidal germination strategy Kountche et al. 2019). ...
... Frischmuth et al. (1991) reported the first synthesis of 5-deoxystrigol together with other analogues based on functionalization at C-5 with hydroxyl or acetate groups. Alternative synthetic strategies were published later (Reizelman et al. 2000;Shoji et al. 2009), including the synthesis of 5-deoxystrigol together with its C-2 0 epimer, and their C-ring stereoisomers (the latter, corresponding with analogues of orobanchol, namely 4-deoxyorobanchol), reported by Lachia et al. (2014a) (route A in Scheme 26). The first steps result in the acid 54, which then forms an amide with (S,S)-or (R,R)-2,5bis(methoxymethyl)pyrrolidine. ...
... The final GR24 derivatives presented herein are the promising strigolactams reported by Lachia et a
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